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• W4212924302 abstract "Nitrogen oxide (NOx) conversion is an important process for balancing the global nitrogen cycle. Distinct from the biological NOx transformation, we have devised a synthetic approach to this issue by utilizing a bifunctional metal catalyst for producing value-added products from NOx. Here, we present a novel catalysis based on a Ni pincer system, effectively converting Ni-NOx to Ni-NO via deoxygenation with CO(g). This is followed by transfer of the in situ generated nitroso group to organic substrates, which favorably occurs at the flattened Ni(I)-NO site via its nucleophilic reaction. Successful catalytic production of oximes from benzyl halides using NaNO2 is presented with a turnover number of >200 under mild conditions. In a key step of the catalysis, a nickel(I)-•NO species effectively activates alkyl halides, which is carefully evaluated by both experimental and theoretical methods. Our nickel catalyst effectively fulfills a dual purpose, namely, deoxygenating NOx anions and catalyzing C-N coupling." @default.
• W4212924302 created "2022-02-24" @default.
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• W4212924302 date "2022-02-14" @default.
• W4212924302 modified "2023-10-15" @default.
• W4212924302 title "Nickel-Catalyzed NO Group Transfer Coupled with NO_<i>x</i> Conversion" @default.
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• W4212924302 doi "https://doi.org/10.1021/jacs.1c13560" @default.
• W4212924302 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35157442" @default.
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