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- W4212961689 abstract "Abstract The generation of diphosphorus molecules P 2 under mild conditions in solution is a useful strategy to generate diphosphines via [4+2] cycloadditions. We recently described the release of P 2 units from the nickel butterfly complex [{(IMes)Ni(CO)} 2 (μ 2 ,η 2 :η 2 ‐P 2 )] (IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazolin‐2‐ylidene) upon addition of CO gas. Herein, we developed an alternative protocol for the same process using heterocumulenes. In addition to formation of P 4 (the dimerisation product of P 2 ), the reactions afford nickel complexes of novel pincer‐type ligands. Aryl isothiocyanates undergo a trimerisation within the coordination sphere of nickel and afford square planar nickel complexes with S−C−S pincer‐ligand frameworks. Carbon disulfide coordinates to the [(IMes)Ni]‐fragment in an η 2 ‐fashion, affording a dinuclear complex. Similar products are formed when the N‐heterocyclic carbene nickel(0) complex [(IMes)Ni(vtms) 2 ] is used as a precursor (vtms=vinyltrimethylsilane)." @default.
- W4212961689 created "2022-02-24" @default.
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- W4212961689 date "2022-03-14" @default.
- W4212961689 modified "2023-09-25" @default.
- W4212961689 title "Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes" @default.
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- W4212961689 doi "https://doi.org/10.1002/ejic.202101057" @default.
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