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- W4213013014 endingPage "120877" @default.
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- W4213013014 abstract "The reaction of Fe(NO3)3·9H2O, sodium thiocyanate, and N-(2-pyridylmethyl)iminodiisopropanol (H2pmidip) in methanol/water mixture solution leads to the formation of a mononuclear iron(III) compound of [FeIII(Hpmidip)(NCS)2] (1). The iron ion of 1 has a distorted octahedral structure that is bonded by two thiocyanate anions and one Hpmidip- ligand. One of the two hydroxyl moieties in H2pmidip is deprotonated, while the other is involved in hydrogen bonding interactions to form a dimeric structure. The magnetic properties of 1 reveal a very weak antiferromagnetic interaction within the dimer with parameters J = -0.75 cm−1 and g = 2.068. 1 showed that the catalytic oxidations for a variety of olefins are selective and effective with moderate yields using meta-chloroperoxybenzoic acid (m-CPBA). For the identification of the mechanism for olefin epoxidation in 1, the OO bond cleavage of peroxyphenylacetic acid (PPAA) and competitive experiments of cis- and trans-2-octene have been investigated." @default.
- W4213013014 created "2022-02-24" @default.
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- W4213013014 date "2022-05-01" @default.
- W4213013014 modified "2023-09-26" @default.
- W4213013014 title "A monomeric iron(III) compound containing N-(2-pyridylmethyl)iminodiisopropanolate and thiocyanato ligands: structure, magnetic and catalytic properties" @default.
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- W4213013014 doi "https://doi.org/10.1016/j.ica.2022.120877" @default.
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