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• W4213065296 abstract "We report the formation of a 3D body-centred self-assembled superlattice of gold nanoparticles whose interparticle gap, and hence its plasmonic properties, are adjustable exclusively in the xy-plane. Thus, even though the particles are spherical, their anisotropic packing generates tailorable plasmonic dichroism. The gold nanoparticles are coated with forked ligands containing two mesogens: either two cholesterols (twin), one cholesterol and one azobenzene (Janus), or a mixture of the two. Beside the body-centered arrangement of gold nanoparticles, the structure also contains unusual two-dimensionally x-y dual undulated (eggbox-like) smectic-like layers of mesogens. Moreover, the presence of azobenzene mesogens allows the superlattice to be melted through UV-induced photo-isomerization; the process is reversible displaying low fatigue on repeated cycling." @default.
• W4213065296 created "2022-02-24" @default.
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• W4213065296 date "2022-03-08" @default.
• W4213065296 modified "2023-10-14" @default.
• W4213065296 title "Self‐assembly of Gold Nanoparticles into an Adjustable Plasmonic 3D Lattice using Janus‐type Forked Mesogenic Ligands" @default.
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• W4213065296 doi "https://doi.org/10.1002/asia.202200057" @default.
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