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- W4213090653 abstract "Abstract Reversible encapsulation of CH 2 Cl 2 or Xe in a non‐porous solid‐state molecular organometallic framework of [Rh(Cy 2 PCH 2 PCy 2 )(NBD)][BAr F 4 ] occurs in single‐crystal to single‐crystal transformations. These processes are probed by solid‐state NMR spectroscopy, including 129 Xe SSNMR. Non‐covalent interactions with the ‐CF 3 groups, and hydrophobic channels formed, of [BAr F 4 ] − anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes." @default.
- W4213090653 created "2022-02-24" @default.
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- W4213090653 date "2019-10-11" @default.
- W4213090653 modified "2023-10-14" @default.
- W4213090653 title "Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid‐State Molecular Organometallic Framework (Guest@SMOM)" @default.
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- W4213090653 doi "https://doi.org/10.1002/ange.201910539" @default.
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