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• W4213149903 startingPage "318" @default.
• W4213149903 abstract "Polar intermetallics are an intriguing class of compounds with complex relationships between composition and structure that are not fully understood. This work reports a systematic study of the underexplored ternary composition space RE–Au–Tt (RE = La, Ce, Pr, Nd; Tt = Ge, Pb) to expand our knowledge of the intriguing chemistry and diversity achievable with these metallic constituents. These composition spaces are particularly interesting because of the potential to find Au-bearing, highly polar intermetallic compounds. The elements were first reacted through arc welding under an inert atmosphere, followed by annealing at 850 °C. X-ray diffraction of the products identified seven unreported compounds ranging from the simple NaTl-type compounds La1.5Au2Pb0.5 and Nd2–xAu2Pbx to the more structurally complex La5AuPb3 in the Hf5CuSn3-type structure and Pu3Pd4-type RE3Au3Ge (RE = La, Ce, Pr, Nd). First-principles electronic structure calculations investigate the combination of Fermi surface–Brillouin zone interactions, electrostatic interactions, and delocalized metallic bonding that contributes to the formation of these phases. These calculations show that a mixture of electrostatic and metallic bonding plays a dominant role in these phases. The RE–Au–Tt composition space remains full of potential for discovering materials with relevant magnetic and quantum properties, provided the crystal chemistry can be comprehended." @default.
• W4213149903 created "2022-02-24" @default.
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• W4213149903 date "2022-02-21" @default.
• W4213149903 modified "2023-10-16" @default.
• W4213149903 title "From simple to complex crystal chemistry in the RE–Au–Tt systems (RE = La, Ce, Pr, Nd; Tt = Ge, Pb)" @default.
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• W4213149903 doi "https://doi.org/10.1021/acsorginorgau.1c00057" @default.
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• W4213149903 hasPublicationYear "2022" @default.
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