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• W4213228302 endingPage "114709" @default.
• W4213228302 startingPage "114709" @default.
• W4213228302 abstract "The degradation of phenolic compounds through persulfate (PS) activation is a valuable approach for soil/groundwater remediation. Several reports have been made related to PS activation and contaminant degradation using carbo-catalysts; however, there is no detailed study on soil remediation by colloidal activated carbon. This study demonstrates the phenol (PhOH) degradation efficiency in spiked and field-contaminated soils by a novel and low-cost ball-milled colloidal activated carbon (CACBM) catalyst. The CACBM/PS system exhibited outstanding degradation performance for PhOH in both spiked and field-contaminated soils. Optimum condition for degradation of 5.63 mmol PhOH kg soil-1 was achieved at 2.5 mg CACBM g soil-1, 5 mM PS, and a solid-liquid ratio of 1:5 at 25 °C in the wide pH range of 3-11. Radical scavenger experiments and electron spin resonance (ESR) spectroscopy revealed that both radical (•OH and SO4•-) and non-radical (1O2) species were involved in the CACBM/PS system. PhOH degradation in soil phase followed several degradation pathways, resulting in various intermediate byproducts such as acetic acid, maleic acid, p-benzoquinone, fumaric acid, and ferulic acid as analyzed by ultra-high-performance liquid chromatography with mass spectroscopy (UPLC-MS). The CACBM/PS system showed a promising potential in the remediation of organic-contaminated soil." @default.
• W4213228302 created "2022-02-24" @default.
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• W4213228302 date "2022-05-01" @default.
• W4213228302 modified "2023-10-16" @default.
• W4213228302 title "Remediation of phenol contaminated soil using persulfate activated by ball-milled colloidal activated carbon" @default.
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• W4213228302 doi "https://doi.org/10.1016/j.jenvman.2022.114709" @default.
• W4213228302 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35219205" @default.
• W4213228302 hasPublicationYear "2022" @default.
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