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- W4213237354 abstract "Sufficient understanding on the formation mechanism of the La(Fe,Si)13 phase (1:13 or τ1) in La–Fe–Si alloys would be helpful in optimizing the parameters for high-temperature annealing. In-situ annealing experiments of a centrifugally as-cast LaFe11.6Si1.4 plate were performed by using a differential scanning calorimeter (DSC) in the present study. We confirmed that the τ1 phase is resulted from a peritectic reaction between La-rich liquid phase and α(Fe) solid phase when isothermal annealing at 1423 K. A new finding of a eutectoid decomposition that may occur within the residual La-rich liquid phase upon cooling was revealed. The isothermal transformation kinetics of the τ1 phase in the as-cast plate followed a simplified model of diffusion-controlled continuous network growth. The isothermal entropy change (|ΔSM|) was calculated using the Maxwell equation on M−H data. The maximum |ΔSM| value reached 26.89 J/(kg·K) under 30 kOe in the LaFe11.6Si1.4 sample annealed at 1423 K for 120 min." @default.
- W4213237354 created "2022-02-24" @default.
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- W4213237354 date "2022-06-01" @default.
- W4213237354 modified "2023-10-16" @default.
- W4213237354 title "Revisiting high-temperature phase transition and magnetocaloric effect of LaFe11.6Si1.4 alloy" @default.
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- W4213237354 doi "https://doi.org/10.1016/j.jmmm.2022.169168" @default.
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