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• W4213274268 endingPage "337" @default.
• W4213274268 startingPage "326" @default.
• W4213274268 abstract "Abstract An important mechanism of carbonate mineral growth is dissolution-reprecipitation, including the transformation of amorphous precursor to crystalline carbonates, and coarsening (ripening) of fine carbonate crystals. However, the mechanistic details of cation exchange associated with carbonate mineral growth via a dissolution-reprecipitation process are still not well understood. In this study, we used Mg isotopes to probe the exchange of Mg between aqueous solutions and norsethite [BaMg(CO3)2] by systematic synthesis experiments. Norsethite is a model double carbonate, with a general formula of AB(CO3)2, where A and B stand for two different divalent ions. Formation of norsethite is comprised of three stages, including: (1) precipitation of barium-magnesium (Ba-Mg) amorphous carbonate; (2) transformation of Ba-Mg amorphous carbonate to nano-crystalline norsethite by fast dissolution-reprecipitation; and (3) coarsening (ripening) of nano-norsethite by slow dissolution-reprecipitation. Magnesium isotopes displayed distinct fractionation behaviors in each of the three stages. The Mg isotope fractionation factors (∆26Mgsolid-aq) associated with precipitation of Ba-Mg amorphous carbonate were slightly negative and temperature-dependent, from –0.83‰ at 30 °C to –0.53‰ at 70 °C. During the transformation of Ba-Mg amorphous carbonate to nano-crystalline norsethite, isotopically light Mg isotopes were further enriched in the solid phase, with apparent ∆26Mgsolid-aq decreasing to –2.12‰ at 30 °C and –1.56‰ at 70 °C. In the ripening stage, norsethite became isotopically heavier, with ∆26Mgsolid-aq increasing up to –1.95‰ at 30 °C and –1.17‰ at 70 °C. The experimental results show that non-equilibrium isotope fractionation occurred during the transformation of amorphous carbonate to nano-crystalline norsethite (i.e., fast dissolution-reprecipitation). By contrast, the subsequent ripening of the norsethite led to the evolution toward isotopic equilibrium of the system by slower exchange with a longer reaction time (i.e., slow dissolution-reprecipitation). Moreover, our first-principles calculation results indicate that the equilibrium isotope fractionation was approached, but not attained, even after 276 days of recrystallization at temperatures below 70 °C. In short, this study has identified two different types of dissolution-reprecipitation process during the carbonate mineral growth and highlights the importance of understanding formation mechanism and post-depositional history of carbonate in interpreting the isotopic data of carbonate minerals." @default.
• W4213274268 created "2022-02-24" @default.
• W4213274268 creator A5009578701 @default.
• W4213274268 creator A5066273747 @default.
• W4213274268 creator A5086048857 @default.
• W4213274268 date "2023-02-01" @default.
• W4213274268 modified "2023-09-27" @default.
• W4213274268 title "Isotopic responses of magnesium to two types of dissolution-reprecipitation processes for the growth of the double-carbonate mineral norsethite" @default.
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