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- W4213302342 endingPage "1959" @default.
- W4213302342 startingPage "1951" @default.
- W4213302342 abstract "The solid-state phase transformation in nickel(II) bis(diisopropyldithiocarbonate) is analyzed using a combination of high-speed in situ single-crystal diffraction, terahertz spectroscopy, optical microscopy, thermal analysis, and density functional theory. We show that the monoclinic P21/c structure of this compound undergoes a displacive phase change at about 3 °C. The monoclinic angles and unit cell volumes change reversibly between 110.3°/2265 Å3 and 103.8°/2168 Å3. An analysis of atomic positions using high-resolution in situ synchrotron X-ray diffraction data revealed details of the atomic displacements that show a change in order that precedes and accompanies the change in structure. The structural changes are rapid and are manifested as reversible macroscale crystal movement and jumping (thermosalience) and represent the first case of thermosalience in dithiocarbamate complexes." @default.
- W4213302342 created "2022-02-24" @default.
- W4213302342 creator A5007745751 @default.
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- W4213302342 creator A5075538999 @default.
- W4213302342 creator A5080269360 @default.
- W4213302342 creator A5080826701 @default.
- W4213302342 date "2022-02-17" @default.
- W4213302342 modified "2023-10-13" @default.
- W4213302342 title "Thermosalience Revealed on the Atomic Scale: Rapid Synchrotron Techniques Uncover Molecular Motion Preceding Crystal Jumping" @default.
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- W4213302342 doi "https://doi.org/10.1021/acs.cgd.1c01495" @default.