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- W4213303034 abstract "The selective hydrogenation of soybean methyl ester, short chain dienes, and cyclooctadiene to the monoene stage under the catalytic influence of [Pt(PO3)2(SnCl3)Cl] is described. In this catalyst, the platinum can be replaced by palladium, the phosphorus by arsenic, antimony, sulfur, or selenium, the phenyl groups by other aromatic, aliphatic, or ester groups, the tin by lead or germanium, and the chlorine by bromine, iodine, or cyanogen. Terminal double bonds, even in monoenes, are hydrogenated. Isomerization to conjugation apparently precedes hydrogenation. Under mild conditions only isomerization is observed. The isomerized products are largely in the trans form. The catalyst, when made heterogeneous by attaching it to cross-linked polystyrene, still retains its ability to hydrogenate polyunsaturated molecules selectively." @default.
- W4213303034 created "2022-02-24" @default.
- W4213303034 date "1979-05-05" @default.
- W4213303034 modified "2023-09-25" @default.
- W4213303034 title "Inorganic Compounds with Unusual Properties—II" @default.
- W4213303034 doi "https://doi.org/10.1021/ba-1979-0173" @default.
- W4213303034 hasPublicationYear "1979" @default.
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