FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4213306865> ?p ?o ?g. }

• W4213306865 endingPage "036505" @default.
• W4213306865 startingPage "036505" @default.
• W4213306865 abstract "Many kinetic studies on hydrogen evolution reaction (HER) were done in N 2 saturated solutions in order to avoid possible H 2 leakage, which results in a variation of H 2 concentration at the electrode/electrolyte interface ( <?CDATA ${c}_{{{rm{H}}}_{2}}^{{rm{s}}}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msubsup> <mml:mrow> <mml:mi>c</mml:mi> </mml:mrow> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi mathvariant=normal>H</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> </mml:mrow> <mml:mrow> <mml:mi mathvariant=normal>s</mml:mi> </mml:mrow> </mml:msubsup> </mml:math> ). It will induce the drift of equilibrium potential (E eq ) and applied activation overpotential ( η act ) for HER. Consequently, it may result in errors for estimating the kinetic parameters for HER. By taking HER at Pt(111) under RDE configuration as a model reaction, quantitative relation among <?CDATA ${c}_{{{rm{H}}}_{2}}^{{rm{s}}}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msubsup> <mml:mrow> <mml:mi>c</mml:mi> </mml:mrow> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi mathvariant=normal>H</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> </mml:mrow> <mml:mrow> <mml:mi mathvariant=normal>s</mml:mi> </mml:mrow> </mml:msubsup> </mml:math> and the reaction current density (j) is established based on the mass transport equations. From the j– η act plots, our results reveal that i) with the increase of HER current, the equivalent <?CDATA ${c}_{{{rm{H}}}_{2}}^{{rm{s}}}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msubsup> <mml:mrow> <mml:mi>c</mml:mi> </mml:mrow> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi mathvariant=normal>H</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> </mml:mrow> <mml:mrow> <mml:mi mathvariant=normal>s</mml:mi> </mml:mrow> </mml:msubsup> </mml:math> increases, which accompanies with a drift of thermodynamic equilibrium potential (E eq ) for HER decreases; ii) when η act is negative of −50 mV, the j– η act plot for HER is the same in N 2 and H 2 saturated solution, with a slope of 30 mV Dec −1 ; Our results suggest that HER activity should be compared in solutions with the same composition and at the same activation overpotential instead of at the same applied potential. Proper experimental methods for post data analysis are proposed in order to derive the intrinsic HER kinetics." @default.
• W4213306865 created "2022-02-24" @default.
• W4213306865 creator A5013382299 @default.
• W4213306865 creator A5015542909 @default.
• W4213306865 creator A5017541508 @default.
• W4213306865 creator A5027895884 @default.
• W4213306865 creator A5041017754 @default.
• W4213306865 creator A5080298787 @default.
• W4213306865 creator A5088607744 @default.
• W4213306865 date "2022-03-01" @default.
• W4213306865 modified "2023-09-30" @default.
• W4213306865 title "Effect of Hydrogen Pressure on the Intrinsic Kinetics of Hydrogen Evolution Reaction at Pt(111) Electrode" @default.
• W4213306865 cites W1966720567 @default.
• W4213306865 cites W1973782069 @default.
• W4213306865 cites W1974984468 @default.
• W4213306865 cites W1979369735 @default.
• W4213306865 cites W1982414605 @default.
• W4213306865 cites W1985618996 @default.
• W4213306865 cites W1985938896 @default.
• W4213306865 cites W1987490519 @default.
• W4213306865 cites W1997216543 @default.
• W4213306865 cites W2006507218 @default.
• W4213306865 cites W2018546218 @default.
• W4213306865 cites W2028180964 @default.
• W4213306865 cites W2046565700 @default.
• W4213306865 cites W2093065207 @default.
• W4213306865 cites W2119916225 @default.
• W4213306865 cites W2135733817 @default.
• W4213306865 cites W2162415014 @default.
• W4213306865 cites W2205880320 @default.
• W4213306865 cites W2306757740 @default.
• W4213306865 cites W2335971894 @default.
• W4213306865 cites W2338864617 @default.
• W4213306865 cites W2410039023 @default.
• W4213306865 cites W2601810133 @default.
• W4213306865 cites W2615982391 @default.
• W4213306865 cites W2760701841 @default.
• W4213306865 cites W2805871080 @default.
• W4213306865 cites W28411063 @default.
• W4213306865 cites W2902539774 @default.
• W4213306865 cites W2939634025 @default.
• W4213306865 cites W2946052204 @default.
• W4213306865 cites W2956067998 @default.
• W4213306865 cites W2968691008 @default.
• W4213306865 cites W2973074650 @default.
• W4213306865 cites W3036102895 @default.
• W4213306865 cites W3057334483 @default.
• W4213306865 cites W3118443777 @default.
• W4213306865 cites W3131685164 @default.
• W4213306865 cites W3190430535 @default.
• W4213306865 cites W3209078466 @default.
• W4213306865 doi "https://doi.org/10.1149/1945-7111/ac5796" @default.
• W4213306865 hasPublicationYear "2022" @default.
• W4213306865 type Work @default.
• W4213306865 citedByCount "2" @default.
• W4213306865 countsByYear W42133068652022 @default.
• W4213306865 countsByYear W42133068652023 @default.
• W4213306865 crossrefType "journal-article" @default.
• W4213306865 hasAuthorship W4213306865A5013382299 @default.
• W4213306865 hasAuthorship W4213306865A5015542909 @default.
• W4213306865 hasAuthorship W4213306865A5017541508 @default.
• W4213306865 hasAuthorship W4213306865A5027895884 @default.
• W4213306865 hasAuthorship W4213306865A5041017754 @default.
• W4213306865 hasAuthorship W4213306865A5080298787 @default.
• W4213306865 hasAuthorship W4213306865A5088607744 @default.
• W4213306865 hasConcept C185592680 @default.
• W4213306865 hasConceptScore W4213306865C185592680 @default.
• W4213306865 hasFunder F4320321001 @default.
• W4213306865 hasIssue "3" @default.
• W4213306865 hasLocation W42133068651 @default.
• W4213306865 hasOpenAccess W4213306865 @default.
• W4213306865 hasPrimaryLocation W42133068651 @default.
• W4213306865 hasRelatedWork W1531601525 @default.
• W4213306865 hasRelatedWork W1990781990 @default.
• W4213306865 hasRelatedWork W2384464875 @default.
• W4213306865 hasRelatedWork W2606230654 @default.
• W4213306865 hasRelatedWork W2607424097 @default.
• W4213306865 hasRelatedWork W2748952813 @default.
• W4213306865 hasRelatedWork W2899084033 @default.
• W4213306865 hasRelatedWork W2948807893 @default.
• W4213306865 hasRelatedWork W2952652699 @default.
• W4213306865 hasRelatedWork W2778153218 @default.
• W4213306865 hasVolume "169" @default.
• W4213306865 isParatext "false" @default.
• W4213306865 isRetracted "false" @default.
• W4213306865 workType "article" @default.