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- W4213309611 abstract "Abstract Electrophilic cyanation of the lithiated cymantrenes [(C 5 X 4 Li)Mn(CO) 3 ] (X = H, Cl) yields the corresponding monocyanocymantrenes [(C 5 X 4 CN)Mn(CO) 3 ] ( 1 , 3 ). UV irradiation of 1 in the presence of PPh 3 leads to the formation of [(C 5 H 4 CN)Mn(CO) 2 PPh 3 ] ( 2 ). The molecular and crystal structures of 1 , 2 and 3 were determined. The cyano groups take part in intermolecular C-X⋯N (X = H, Cl) interactions for all compounds. Graphical Abstract" @default.
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- W4213309611 date "2022-02-18" @default.
- W4213309611 modified "2023-09-25" @default.
- W4213309611 title "Synthesis, Molecular and Crystal Structures of Some Monocyanocymantrenes" @default.
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- W4213309611 doi "https://doi.org/10.1007/s10870-022-00929-1" @default.
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