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- W4213367777 abstract "The possibility of isovalent substitution in the In-sublattice of layered perovskite BaLaInO4 was experimentally investigated. The yttrium doping leads to the increase of total and protonic conductivity up to 2 orders of magnitude. The solid solution BaLaIn1−xYxO4 (0 ≤ x ≤ 0.5) is mixed ionic-electronic (hole) conductor at the dry air. The increase in the water vapor partial pressure leads to the appearance of protons in the structure below 600 °C, which is confirmed by the decrease of activation energy from ∼0.75 eV to ∼0.52 eV for doped samples. Both undoped and doped BaLaIn1−xYxO4 samples are nearly pure (∼95%) proton conductors under wet air conditions below 400 °C. The most conductive Y-doped compositions BaLaIn0.8Y0.2O4 demonstrates the proton conductivity value 4∙10−5 S/cm at the 400 °C." @default.
- W4213367777 created "2022-02-24" @default.
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- W4213367777 date "2022-06-01" @default.
- W4213367777 modified "2023-09-25" @default.
- W4213367777 title "Novel mid-temperature Y3+ → In3+ doped proton conductors based on the layered perovskite BaLaInO4" @default.
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- W4213367777 doi "https://doi.org/10.1016/j.ceramint.2022.02.102" @default.
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