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- W4213378563 abstract "[13780-57-9] ClF5S (MW 162.51) InChI = 1S/ClF5S/c1-7(2,3,4,5)6 InChIKey = GSYNTTDHMKSMFY-UHFFFAOYSA-N (reagent used for the incorporation of the SF5 group into organic molecules) Physical Data: mp −64 °C; bp −21 °C. Solubility: soluble in most organic solvents. Form Supplied in: colorless gas packaged in cylinders, commercially available. Analysis of Reagent Purity: IR,1 19F NMR,2 Raman spectrum.1a,1b,3 Preparative Methods: there are several practical methods of preparation of pentafluorosulfanyl chloride. It could be formed rapidly (1 h) and in high yield (92%) by room-temperature reaction of SF4 with ClF in the presence of activated CsF (eq 1).4 The compound is also prepared from the reaction of sulfur tetrafluoride (SF4), chlorine, and CsF in high yield at elevated temperatures (eq 2).5 A high yield and inexpensive preparation of SF5Cl from sulfur tetrafluoride, Cl2, and KF has also been described, but a much longer reaction time is required at relatively high temperatures (eq 3).6 (1) (2) (3) Purification: fractionated through a low-temperature column. Handling, Storage, and Precautions: pentafluorosulfanyl chloride is stable at room temperature. Since it is toxic, it should be used in a fume hood." @default.
- W4213378563 created "2022-02-24" @default.
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- W4213378563 date "2020-07-24" @default.
- W4213378563 modified "2023-10-10" @default.
- W4213378563 title "Pentafluorosulfanyl Chloride" @default.
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- W4213378563 doi "https://doi.org/10.1002/047084289x.rn00413.pub2" @default.
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