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- W4213421312 abstract "In a non-aqueous medium, oxidation kinetics of thioglycolic, thiolactic and thiomalic acids by benzimidazolium dichromate have been studied. In the temperature range of 20°C–50°C, oxidation kinetics were examined by spectrophotometry. In terms of oxidant, the reaction is dependent on the unitary order. In the case of thioacids, we find the Michaelis-Menten type kinetics. Hydrogen-ions act as catalyst in this process. The reaction rate slows down as the Mn2+ ion concentration increases. The reaction does not cause acrylonitrile to polymerize. The formation of a thioester into the pre-equilibrium followed by its progressive degradation was postulated as a mechanism." @default.
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- W4213421312 date "2022-02-01" @default.
- W4213421312 modified "2023-09-26" @default.
- W4213421312 title "Evaluation of kinetic parameters for oxidation of thioacids by benzimidazolium dichromate: A mechanistic study" @default.
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- W4213421312 doi "https://doi.org/10.1016/j.jics.2022.100390" @default.
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