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• W4213441567 endingPage "6514" @default.
• W4213441567 startingPage "6508" @default.
• W4213441567 abstract "Fe3C modified by the incorporation of carbon materials offers excellent electrical conductivity and interfacial lithium storage, making it attractive as an anode material in lithium-ion batteries. In this work, we describe a time- and energy-saving approach for the large-scale preparation of Fe3C nanoparticles embedded in mesoporous carbon nanosheets (Fe3C-NPs@MCNSs) by solution combustion synthesis and subsequent carbothermal reduction. Fe3C nanoparticles with a diameter of ∼5 nm were highly crystallized and compactly dispersed in mesoporous carbon nanosheets with a pore-size distribution of 3-5 nm. Fe3C-NPs@MCNSs exhibited remarkable high-rate lithium storage performance with discharge specific capacities of 731, 647, 481, 402 and 363 mA h g-1 at current densities of 0.1, 1, 2, 5 and 10 A g-1, respectively, and when the current density reduced back to 0.1 A g-1 after 45 cycles, the discharge specific capacity could perfectly recover to 737 mA h g-1 without any loss. The unique structure could promote electron and Li-ion transfer, create highly accessible multi-channel reaction sites and buffer volume variation for enhanced cycling and good high-rate lithium storage performance." @default.
• W4213441567 created "2022-02-25" @default.
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• W4213441567 date "2022-01-01" @default.
• W4213441567 modified "2023-10-15" @default.
• W4213441567 title "Large-scale synthesis of ultrafine Fe₃C nanoparticles embedded in mesoporous carbon nanosheets for high-rate lithium storage" @default.
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• W4213441567 doi "https://doi.org/10.1039/d1ra08516f" @default.
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