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- W4214547140 endingPage "4240" @default.
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- W4214547140 abstract "A highly regioselective inverse electron-demand aza-Diels-Alder reaction of α,β-unsaturated thioesters with 1,2-diaza-1,3-dienes generated in situ from α-halogeno hydrazones was developed. With α,β-unsaturated thioesters as C═S dienophiles, the developed protocol enables the formation of diverse 3,6-dihydro-2H-1,3,4-thiadiazine derivatives in excellent yields. In the presence of lithium aluminum hydride, 3,6-dihydro-2H-1,3,4-thiadiazine derivatives could be further transformed into 5,6-dihydro-4H-1,3,4-thiadiazines in good yields." @default.
- W4214547140 created "2022-03-02" @default.
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- W4214547140 date "2022-02-25" @default.
- W4214547140 modified "2023-10-15" @default.
- W4214547140 title "Inverse Electron-Demand Aza-Diels–Alder Reaction of α,β-Unsaturated Thioesters with In Situ-Generated 1,2-Diaza-1,3-dienes for the Synthesis of 1,3,4-Thiadiazines" @default.
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- W4214547140 doi "https://doi.org/10.1021/acs.joc.1c03072" @default.
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