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- W4214586474 abstract "This chapter focuses on the chemical reactions that occur in all states of matter—gas, liquid, and solid. The subject of chemical kinetics is the study of the rates at which chemical reactions occur. It is the study of the rates at which chemical compounds interact with one another to produce new chemical species, besides the insight into factors governing chemical reactivity that derives from them. The rates of chemical change span an enormous range of time scales—from the slowness of geologic change to the speed of detonations and explosions. The transformation of a reactant into a final product is known as an “overall reaction,” or “stoichiometric reaction.” Research on the kinetics of overall reactions has served to characterize chemical reactions important to broad areas of science and to lay down the basic principles of the field. Most chemical reactions occur via the intermediacy of highly reactive chemical species such as atoms, free radicals, and ions; that are not detected by classical analytical methods and go unnoticed unless special efforts are made. The development of highly sensitive spectroscopies, molecular-beam technology, and rapid-response electronics led to experimental methods for probing translational, vibrational, rotational, and electronic energy states during elementary chemical reactions. Elementary reactions describe the fundamental chemistry underlying any overall reaction, and chemical dynamics provides insights into the details of how an elementary reaction occurs." @default.
- W4214586474 created "2022-03-02" @default.
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- W4214586474 date "2007-01-01" @default.
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- W4214586474 title "Chapter 1 Introduction" @default.
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- W4214586474 doi "https://doi.org/10.1016/s0069-8040(07)42001-5" @default.
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