FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4214599020> ?p ?o ?g. }

• W4214599020 endingPage "107176" @default.
• W4214599020 startingPage "107176" @default.
• W4214599020 abstract "Homonuclear isotropic mixing modules allow J-coupled spins to exchange magnetization even when separated by chemical shift offsets that exceed their couplings. This is exploited in TOtal Correlation SpectroscopY (TOCSY) experiments and its variants, which facilitate these homonuclear polarization exchanges by applying broadband RF pulses. These then establish an effective Hamiltonian in which chemical shift offsets are erased, while J-coupling terms -including flip-flop components- remain active. The polarization that these non-secular terms will transfer among systems of chemically inequivalent sites over the course of a mixing period, are widely used modules in 1D and in multidimensional liquid-state NMR. Homonuclear correlation experiments are also common in solids NMR, particularly among X = 13C or 15N nuclei. Solids NMR experiments are often challenged by high-power RF demands which have led to a family of homonuclear solid-state correlation experiments that avoid pulsing on the nuclei of interest, and focus instead on the 1Hs that are bonded to them. These solid experiments usually reintroduce/strengthen 1H-X dipolar couplings; these, in conjunction with assistance from rotational resonance effects, bring back the truncated X-X dipolar interactions and facilitate the generation of cross peaks. The present study explores whether a similar goal can be achieved for solution-state counterparts, based on the reintroduction of truncated flip-flop terms in the J-coupling Hamiltonian via the pulsing on other, heteronuclear species. A proposal to achieve this is derived, and the resulting HOmonucleaR Recoupling by hEteroNuclear DecOUplingS (HORRENDOUS) approach to provide correlations between like nuclei without pulsing on them, is demonstrated." @default.
• W4214599020 created "2022-03-02" @default.
• W4214599020 creator A5060800875 @default.
• W4214599020 creator A5065091727 @default.
• W4214599020 creator A5071742208 @default.
• W4214599020 creator A5089316162 @default.
• W4214599020 date "2022-04-01" @default.
• W4214599020 modified "2023-10-17" @default.
• W4214599020 title "HORRENDOUS NMR: Establishing correlations in solution-state NMR by reinstating non-secular J-coupling terms" @default.
• W4214599020 cites W1964921286 @default.
• W4214599020 cites W1969270088 @default.
• W4214599020 cites W1973061874 @default.
• W4214599020 cites W1980873042 @default.
• W4214599020 cites W1987924925 @default.
• W4214599020 cites W1996911308 @default.
• W4214599020 cites W2001334693 @default.
• W4214599020 cites W2006731694 @default.
• W4214599020 cites W2024487739 @default.
• W4214599020 cites W2031182089 @default.
• W4214599020 cites W2034121963 @default.
• W4214599020 cites W2035628504 @default.
• W4214599020 cites W2036921365 @default.
• W4214599020 cites W2045458872 @default.
• W4214599020 cites W2046544915 @default.
• W4214599020 cites W2052553291 @default.
• W4214599020 cites W2057913703 @default.
• W4214599020 cites W2063988821 @default.
• W4214599020 cites W2067939538 @default.
• W4214599020 cites W2090647948 @default.
• W4214599020 cites W2090653967 @default.
• W4214599020 cites W2138456893 @default.
• W4214599020 cites W2144406846 @default.
• W4214599020 cites W2165938053 @default.
• W4214599020 cites W2603967212 @default.
• W4214599020 cites W2995780560 @default.
• W4214599020 cites W4251673379 @default.
• W4214599020 doi "https://doi.org/10.1016/j.jmr.2022.107176" @default.
• W4214599020 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35272112" @default.
• W4214599020 hasPublicationYear "2022" @default.
• W4214599020 type Work @default.
• W4214599020 citedByCount "0" @default.
• W4214599020 crossrefType "journal-article" @default.
• W4214599020 hasAuthorship W4214599020A5060800875 @default.
• W4214599020 hasAuthorship W4214599020A5065091727 @default.
• W4214599020 hasAuthorship W4214599020A5071742208 @default.
• W4214599020 hasAuthorship W4214599020A5089316162 @default.
• W4214599020 hasBestOaLocation W42145990201 @default.
• W4214599020 hasConcept C121332964 @default.
• W4214599020 hasConcept C126255220 @default.
• W4214599020 hasConcept C130787639 @default.
• W4214599020 hasConcept C140463767 @default.
• W4214599020 hasConcept C150769733 @default.
• W4214599020 hasConcept C153202636 @default.
• W4214599020 hasConcept C159467904 @default.
• W4214599020 hasConcept C173523689 @default.
• W4214599020 hasConcept C176900771 @default.
• W4214599020 hasConcept C178790620 @default.
• W4214599020 hasConcept C185592680 @default.
• W4214599020 hasConcept C26873012 @default.
• W4214599020 hasConcept C2778870898 @default.
• W4214599020 hasConcept C32909587 @default.
• W4214599020 hasConcept C33923547 @default.
• W4214599020 hasConcept C40447573 @default.
• W4214599020 hasConcept C41999313 @default.
• W4214599020 hasConcept C46141821 @default.
• W4214599020 hasConcept C66974803 @default.
• W4214599020 hasConcept C71240020 @default.
• W4214599020 hasConcept C92381491 @default.
• W4214599020 hasConceptScore W4214599020C121332964 @default.
• W4214599020 hasConceptScore W4214599020C126255220 @default.
• W4214599020 hasConceptScore W4214599020C130787639 @default.
• W4214599020 hasConceptScore W4214599020C140463767 @default.
• W4214599020 hasConceptScore W4214599020C150769733 @default.
• W4214599020 hasConceptScore W4214599020C153202636 @default.
• W4214599020 hasConceptScore W4214599020C159467904 @default.
• W4214599020 hasConceptScore W4214599020C173523689 @default.
• W4214599020 hasConceptScore W4214599020C176900771 @default.
• W4214599020 hasConceptScore W4214599020C178790620 @default.
• W4214599020 hasConceptScore W4214599020C185592680 @default.
• W4214599020 hasConceptScore W4214599020C26873012 @default.
• W4214599020 hasConceptScore W4214599020C2778870898 @default.
• W4214599020 hasConceptScore W4214599020C32909587 @default.
• W4214599020 hasConceptScore W4214599020C33923547 @default.
• W4214599020 hasConceptScore W4214599020C40447573 @default.
• W4214599020 hasConceptScore W4214599020C41999313 @default.
• W4214599020 hasConceptScore W4214599020C46141821 @default.
• W4214599020 hasConceptScore W4214599020C66974803 @default.
• W4214599020 hasConceptScore W4214599020C71240020 @default.
• W4214599020 hasConceptScore W4214599020C92381491 @default.
• W4214599020 hasFunder F4320306076 @default.
• W4214599020 hasFunder F4320320946 @default.
• W4214599020 hasFunder F4320322252 @default.
• W4214599020 hasLocation W42145990201 @default.
• W4214599020 hasLocation W42145990202 @default.
• W4214599020 hasOpenAccess W4214599020 @default.
• W4214599020 hasPrimaryLocation W42145990201 @default.
• W4214599020 hasRelatedWork W20443045 @default.
• W4214599020 hasRelatedWork W21942243 @default.

• next