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- W4214604656 abstract "The effect of coadsorbed CO on dissociation paths of methylamine on Ru(001) has been examined by LEED, TPD and HREELS. It was found that the effect of CO considerably changes as a function of partial CO coverage. For methylamine alone on Ru(001), the C-H and N-H bonds are dissociated simultaneously at 280–320 K. In the presence of low-coverage (~ 0.3) CO molecules, an NH2 species is formed persisting on the surface up to > 350 K, resulting in a relative enhancement of C-H bond scission. In the presence of high-coverage (0.5–0.68) CO, a well ordered (2 × 2) phase forms and partial dehydrogenation of methylamine takes place forming a species containing a CN double bond as a stable intermediate, followed by complete dissociation at higher temperatures." @default.
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- W4214604656 date "1991-06-01" @default.
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- W4214604656 title "Coadsorption of CO and methylamine on Ru(001): effect of coadsorbed CO on dissociation paths of methylamine" @default.
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- W4214604656 doi "https://doi.org/10.1016/0039-6028(91)90826-e" @default.
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