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- W4214610366 abstract "[61777-16-0] C4H7Li (MW 62.05) InChI = 1S/C4H7.Li/c1-4(2)3;/h1-2H2,3H3; InChIKey = UTMOUJZUFALLKY-UHFFFAOYSA-N (methallylating agent in substitutions and additions; used to attach methallyl groups to other metals and nonmetals) Alternate Name: 3-lithio-2-methylpropene. Physical Data: colorless crystals;1 1H, 13C, and 6Li NMR spectra have been reported on solutions.2 Solubility: sol ethers; sparingly sol hydrocarbons.1 Preparative Methods: TMEDA complex by metalating Isobutene with n‐Butyllithium/N,N,N′,N′‐Tetramethylethylenediamine;3 by metalating isobutene with butyllithium/Potassium tert‐Butoxide, and then reacting the methallylpotassium with Lithium Bromide in ether;4 from methallyltin compounds by exchange with Phenyllithium or butyllithium.1 Form Supplied in: prepared in situ and used directly. Handling, Storage, and Precautions: must be prepared and transferred under inert gas to exclude oxygen and moisture." @default.
- W4214610366 created "2022-03-02" @default.
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- W4214610366 date "2001-04-15" @default.
- W4214610366 modified "2023-09-28" @default.
- W4214610366 title "Methallyllithium" @default.
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- W4214610366 doi "https://doi.org/10.1002/047084289x.rm063" @default.
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