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- W4214641579 abstract "Abstract N ‐heterocyclic carbene‐capped cyclodextrin (ICyD) ligands, α‐ICyD and β‐ICyD derived from α‐ and β‐cyclodextrin, respectively give opposite regioselectivities in a copper‐catalyzed hydroboration. The site‐selectivity results from two different mechanisms: the conventional parallel one and a new orthogonal mechanism. The shape of the cavity was shown not only to induce a regioselectivity switch but also a mechanistic switch. The scope of interest of the encapsulation of a reactive center is therefore broadened by this study." @default.
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- W4214641579 date "2017-08-02" @default.
- W4214641579 modified "2023-10-18" @default.
- W4214641579 title "Cyclodextrin Cavity-Induced Mechanistic Switch in Copper-Catalyzed Hydroboration" @default.
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- W4214641579 doi "https://doi.org/10.1002/ange.201705303" @default.
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