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- W4214686586 abstract "Abstract The earth‐metal olefin complex [Ga I (COD) 2 ] + [Al(OR F ) 4 ] − (COD=1,5‐cyclooctadiene; R F =C(CF 3 ) 3 ) constitutes the first homoleptic olefin complex of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and constitutes an olefin complex of a main‐group metal that—similar to many transition‐metals—may adopt the +1 and +3 oxidation states opening potential applications. Crystallographic‐, vibrational‐ and computational investigations give an insight to the atypical bonding between an olefin and a main‐group metal. They are compared to classical transition‐metal relatives." @default.
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- W4214686586 date "2020-10-26" @default.
- W4214686586 modified "2023-10-18" @default.
- W4214686586 title "A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?" @default.
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- W4214686586 doi "https://doi.org/10.1002/ange.202011466" @default.
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