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• W4214710104 endingPage "334" @default.
• W4214710104 startingPage "243" @default.
• W4214710104 abstract "Core-modified porphyrins have been widely investigated and exhibit diverse characteristics. Heteroporphyrins of this type retain the framework found in true porphyrins but have O, S, Se, Te or P replacing one or more of the core nitrogens. Furthermore, heterocarbaporphyrins have core carbon atoms present in addition to heteroatom substitutions and thereby allow for further structural diversity. Major advances have been made over the last 20 years and aromatic, nonaromatic and antiaromatic macrocyclic systems have been synthesized. Heteroporphyrins have been incorporated in nanomolecular arrays and extended conjugated systems have been described. New architectures have been reported, including carbazole-derived structures, and novel combinations of core atoms have been introduced. Heteroporphyrins and related systems exhibit unusual reactivity and undergo rearrangements that can lead to the discovery of further modified porphyrinoid structures. A range of coordination motifs with transition metals have been uncovered and potential catalytic applications have been developed. The review highlights the remarkable advances made in this area since 2001." @default.
• W4214710104 created "2022-03-02" @default.
• W4214710104 creator A5066014054 @default.
• W4214710104 date "2022-01-01" @default.
• W4214710104 modified "2023-10-17" @default.
• W4214710104 title "Recent developments in the chemistry of heteroporphyrins and heterocarbaporphyrins" @default.
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