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- W4214751594 endingPage "118819" @default.
- W4214751594 startingPage "118819" @default.
- W4214751594 abstract "• CT behavior of the antipsychotic drug sulpiride was examined. • The compound was interacted with inorganic and organic acceptors. • The interaction was investigated using two different methodologies. • Three different mechanisms were proposed. Sulpiride is a drug used in therapy for schizophrenia. This drug’s capacity to generate charge-transfer (CT) complexes was investigated and discussed. Its reaction with five different acceptor molecules: tetrafluoro-1,4-benzoquinone (TFQ), chloranilic acid (CLA), 2,3-dichloro-5,6-dicyano- p -benzoquinone (DDQ), 7,7,8,8-tetracyanoquinodimethane (TCNQ), and iodine crystals (I 2 ). These CT complexation reactions generated stable CT complexes at ratios of 1:2 with I 2 and 1:1 with the other acceptors independent of the state (liquid or solid) of the starting materials. Pronounced color changes were observed upon mixing the sulpiride donor with each acceptor in both liquid and solid forms. Using Fourier-transform infrared spectroscopy, UV–Vis spectroscopy, and CHNS elemental measurements, the chemical structure and mechanism of interaction were characterized to assess the synthesized CT complexes." @default.
- W4214751594 created "2022-03-02" @default.
- W4214751594 creator A5052498641 @default.
- W4214751594 creator A5056934831 @default.
- W4214751594 creator A5071167080 @default.
- W4214751594 creator A5073419831 @default.
- W4214751594 date "2022-05-01" @default.
- W4214751594 modified "2023-10-16" @default.
- W4214751594 title "Charge-transfer complexes of antipsychotic drug sulpiride with inorganic and organic acceptors generated through two different approaches: Spectral characterization" @default.
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