Matches in SemOpenAlex for { <https://semopenalex.org/work/W4214768663> ?p ?o ?g. }
- W4214768663 abstract "Abstract Recently, polymer mechanochemistry has attracted much scientific interest due to its potential to develop degradable polymers. When the two ends of a polymer chain experience a linear pulling stress, molecular strain builds up, at sufficiently strong force, a bond scission of the weakest covalent bond results. In contrast, bond‐breaking events triggered by conformational stress are much less explored. Here, we discovered that a Zn salen complex would undergo conformational switching upon allosteric complexation with alkanediammonium guests. By controlling the guest chain length, the torsional strain experienced by Zn complex can be modulated to induce bond cleavage with chemical stimulus, and reactivity trend is predicted by conformational analysis derived by DFT calculation. Such strain‐release reactivity by a Zn(salen) complex initiated by guest binding is reminiscent of conformation‐induced reactivity of enzymes to enable chemical events that are otherwise inhibited." @default.
- W4214768663 created "2022-03-02" @default.
- W4214768663 creator A5021293751 @default.
- W4214768663 creator A5035390856 @default.
- W4214768663 creator A5041050322 @default.
- W4214768663 creator A5051103915 @default.
- W4214768663 creator A5060780862 @default.
- W4214768663 date "2022-03-09" @default.
- W4214768663 modified "2023-10-12" @default.
- W4214768663 title "Allosteric Binding‐Induced Intramolecular Mechanical‐Strain Engineering" @default.
- W4214768663 cites W1251317203 @default.
- W4214768663 cites W1458390031 @default.
- W4214768663 cites W1846677257 @default.
- W4214768663 cites W1965067084 @default.
- W4214768663 cites W1970863842 @default.
- W4214768663 cites W1985280098 @default.
- W4214768663 cites W1988901523 @default.
- W4214768663 cites W1991629012 @default.
- W4214768663 cites W1992389548 @default.
- W4214768663 cites W1997099073 @default.
- W4214768663 cites W1998070214 @default.
- W4214768663 cites W2013786151 @default.
- W4214768663 cites W2023974158 @default.
- W4214768663 cites W2027187383 @default.
- W4214768663 cites W2029693805 @default.
- W4214768663 cites W2039730742 @default.
- W4214768663 cites W2043008468 @default.
- W4214768663 cites W2043738575 @default.
- W4214768663 cites W2044694969 @default.
- W4214768663 cites W2051769448 @default.
- W4214768663 cites W2057315451 @default.
- W4214768663 cites W2057916037 @default.
- W4214768663 cites W2062187697 @default.
- W4214768663 cites W2071712203 @default.
- W4214768663 cites W2083827540 @default.
- W4214768663 cites W2084010281 @default.
- W4214768663 cites W2095859689 @default.
- W4214768663 cites W2126501716 @default.
- W4214768663 cites W2131226967 @default.
- W4214768663 cites W2132828863 @default.
- W4214768663 cites W2134152126 @default.
- W4214768663 cites W2148842814 @default.
- W4214768663 cites W2151709132 @default.
- W4214768663 cites W2169241552 @default.
- W4214768663 cites W2314076703 @default.
- W4214768663 cites W2326038073 @default.
- W4214768663 cites W2328988371 @default.
- W4214768663 cites W2330913969 @default.
- W4214768663 cites W2340816673 @default.
- W4214768663 cites W2415904663 @default.
- W4214768663 cites W2504456333 @default.
- W4214768663 cites W2513817600 @default.
- W4214768663 cites W2522072949 @default.
- W4214768663 cites W2525990640 @default.
- W4214768663 cites W2738342839 @default.
- W4214768663 cites W2742596484 @default.
- W4214768663 cites W2743551468 @default.
- W4214768663 cites W2761440102 @default.
- W4214768663 cites W2765348542 @default.
- W4214768663 cites W2766599711 @default.
- W4214768663 cites W2772060143 @default.
- W4214768663 cites W2790084920 @default.
- W4214768663 cites W2802676778 @default.
- W4214768663 cites W2808341587 @default.
- W4214768663 cites W2816170401 @default.
- W4214768663 cites W2883647989 @default.
- W4214768663 cites W2890352878 @default.
- W4214768663 cites W2896620179 @default.
- W4214768663 cites W2900892138 @default.
- W4214768663 cites W2914747747 @default.
- W4214768663 cites W2918153050 @default.
- W4214768663 cites W2920724391 @default.
- W4214768663 cites W2950529036 @default.
- W4214768663 cites W2957479982 @default.
- W4214768663 cites W2968379845 @default.
- W4214768663 cites W2972207079 @default.
- W4214768663 cites W2996232687 @default.
- W4214768663 cites W2999783969 @default.
- W4214768663 cites W3000274760 @default.
- W4214768663 cites W3009865337 @default.
- W4214768663 cites W3087338457 @default.
- W4214768663 cites W3093643538 @default.
- W4214768663 cites W3094064390 @default.
- W4214768663 cites W3115846121 @default.
- W4214768663 cites W3117748187 @default.
- W4214768663 cites W3120563440 @default.
- W4214768663 cites W3123136583 @default.
- W4214768663 cites W3124820758 @default.
- W4214768663 cites W3177861945 @default.
- W4214768663 cites W3186251949 @default.
- W4214768663 cites W3196700573 @default.
- W4214768663 cites W3217713687 @default.
- W4214768663 cites W4212784831 @default.
- W4214768663 cites W4235055847 @default.
- W4214768663 cites W4237701993 @default.
- W4214768663 cites W4237945133 @default.
- W4214768663 cites W4239360061 @default.
- W4214768663 cites W4243992814 @default.
- W4214768663 cites W4244270357 @default.
- W4214768663 cites W4252349772 @default.