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- W4214826947 abstract "The influence of differently substituted cyclopentadienyl Cp R ligands on the reaction outcome of [Cp R Fe(CO) 2 ] 2 (Cp R = C 5 Me 5 , EtC 5 Me 4 , 1,3-Bu 2 tC 5 H 3 ) with As 4 is examined. For C 5 Me 5 and EtC 5 Me 4 , the pentaarsaferrocene derivatives [Cp R Fe(η 5 -As 5 )] are formed together with [(Cp R Fe) 3 As 6 ] and [(Cp R Fe) 3 As 6 {(η 3 -As 3 )Fe}], while for 1,3-Bu 2 t C 5 H 3 only [(Cp R Fe) 3 As 6 ] is formed. The reaction of [(Me 5 C 5 Fe) 3 As 6 {(η 3 -As 3 )Fe}] with Tl + leads to [{(Me 5 C 5 Fe) 3 As 6 Fe} 2 (μ,η 3 :η 3 -As 3 )] 2+ representing an unexpected dicationic cluster." @default.
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- W4214826947 date "2022-01-01" @default.
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- W4214826947 title "The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic" @default.
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- W4214826947 doi "https://doi.org/10.1016/j.mencom.2022.01.013" @default.
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