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- W4214871857 abstract "Abstract Ozonolytic transformations of ( R )‐(−)‐carvone in aprotic (CH 2 Cl 2 ) and proton‐donor (MeOH) solvents in the presence of pyridine were carried out. A low conversion of the starting diene was noted when carrying out controlled ozonolysis by treatment with equivalent of О 3 . A mixture of 3‐acetyl‐5‐methoxy‐5‐oxopentanoic acid and methyl 4‐oxo‐3‐(2‐oxoethyl)pentanoate in MeOH and 5‐acetyl‐2‐methylcyclohex‐2‐en‐1‐one in CH 2 Cl 2 were formed. Exhaustive ozonolysis of ( R )‐(−)‐carvone in CH 2 Cl 2 in the presence of pyridine leads to 3‐acetylpentadioic acid. The monomethyl ether of 3‐acetylpentadioic acid and the product of its cyclization—2,8‐dioxo‐1‐methylbicyclo[3.3.0]octane‐3,7‐dione were formed in MeOH/Py by the treatment of ozone excess." @default.
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- W4214871857 date "2022-03-01" @default.
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- W4214871857 title "Ozonolytic transformations of ( <i>R</i> )‐(−)‐carvon in the presence of pyridine" @default.
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- W4214871857 doi "https://doi.org/10.1002/jccs.202200035" @default.
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