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- W4214876827 abstract "A mixed-metal 1D coordination polymer [CaCu(HBTC) 2 (H2O) 8 ] n (where H 3 BTC – benzene-1,3,5-tric arboxylic acid) was obtained in a solvothermal synthesis of a well-known copper-containing metal–organic framework [Cu 3 (BTC) 2 (H 2 O) 3 ] n (HKUST-1) in autoclaves 3D-printed from commercial polypropylene. This material was a source of calcium ions, apparently, leaking from a colorant (calcium carbonate) promoted by glacial acetic acid as a modulator used to produce large single crystals of HKUST-1. This finding was confirmed by elemental analysis and a model experiment that resulted in a new calcium-based 1D coordination polymer [Ca(H 2 BTC) 2 (H 2 O) 5 ] n under the same solvothermal conditions with no copper or calcium salts put into a 3D-printed autoclave." @default.
- W4214876827 created "2022-03-05" @default.
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- W4214876827 date "2022-01-01" @default.
- W4214876827 modified "2023-10-03" @default.
- W4214876827 title "Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves" @default.
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- W4214876827 doi "https://doi.org/10.1016/j.mencom.2022.01.034" @default.
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