Matches in SemOpenAlex for { <https://semopenalex.org/work/W4214883325> ?p ?o ?g. }
- W4214883325 endingPage "105" @default.
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- W4214883325 abstract "Solid-state structural studies have been fundamental in the development of single-source precursors (SSPs) for the deposition of thin films of binary semiconductor materials via MOCVD. SSPs are organometallic compounds that contain an M-E covalent bond between the elements that are to be delivered to the substrate. They must be volatile and possess favorable thermal decomposition properties, which include the clean loss of ligand in the gas phase. Structural studies via X-ray crystallography show that many of the molecular compounds studied for this application are in fact oligomeric or polymeric in the solid state. This is a consequence of intermolecular M⋯E bonding that resulted from the availability of empty coordination sites on the metal centers. Ultimately, these additional bonding interactions affect the physical properties of these compounds and their utility as SSPs. This chapter discusses solid-state structures of compounds that have been employed as SSPs for binary group II–VI, III–V, III–VI, IV–VI, and V–VI semiconductor materials, with emphasis on the observed metal bonding environments and intermolecular bonding. Strategies for controlling oligomerization in main group organometallic compounds in the solid state are also presented." @default.
- W4214883325 created "2022-03-05" @default.
- W4214883325 creator A5090093154 @default.
- W4214883325 date "2022-01-01" @default.
- W4214883325 modified "2023-09-26" @default.
- W4214883325 title "Structural studies of main group organometallic single-source precursors for MOCVD" @default.
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