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• W4214891937 endingPage "4304" @default.
• W4214891937 startingPage "4298" @default.
• W4214891937 abstract "Aerobic α-hydroxylation of α-methylene esters has proven challenging due to overoxidation and hydrolysis of the materials. In this article, KOtBu-promoted TBAB-catalyzed α-hydroxylation of α-methylene aryl esters using O2 as the oxygen source has been developed. Both low reaction temperature and catalyst TBAB are keys to success. This reaction provides an environmentally friendly and low-cost approach to mandelates, which are valuable building blocks and widely present in pharmaceuticals." @default.
• W4214891937 created "2022-03-05" @default.
• W4214891937 creator A5038076784 @default.
• W4214891937 creator A5055715984 @default.
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• W4214891937 date "2022-03-04" @default.
• W4214891937 modified "2023-10-14" @default.
• W4214891937 title "Direct Aerobic α-Hydroxylation of Arylacetates for the Synthesis of Mandelates" @default.
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• W4214891937 doi "https://doi.org/10.1021/acs.joc.1c03149" @default.
• W4214891937 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35245055" @default.
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