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- W4214945787 abstract "The four contiguous stereocenters of (−)-swainsonine were efficiently set in a 15-step synthesis with a 15 % overall yield and >99% ee. In order to differeniate the double bond in the key building block oxazolidin-2-one 2, a synthetic equivalent of oxazolidinone 3, is synthesized from the achiral diol 1 followed by a palladium-catalyzed desymmetrization of the meso-bis-carbamate." @default.
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- W4214945787 date "1999-11-05" @default.
- W4214945787 modified "2023-09-23" @default.
- W4214945787 title "cis-5-Amino-6-hydroxycyclohexadiene as a Chiral Building Block: An Asymmetric Synthesis of (−)-Swainsonine" @default.
- W4214945787 doi "https://doi.org/10.1002/(sici)1521-3765(19991105)5:11<3279::aid-chem3279>3.3.co;2-w" @default.
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