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- W4214946079 abstract "The pressure-induced transformation of plane-square complex nickel(II) bis(N,N-diethyldithiocarbamate) between its soft dithiocarbamate (form I) and thioureide (form II) mesomeres is coupled to the interchange of anagostic Ni‧‧‧H−C interactions from methylene to the methyl group, respectively. At 1.23 GPa, the clearly visible giant anomalous compressibility of the crystal reveals a potential-energy difference of 5.4 kJmol-1 between the two complex forms. The structural and spectroscopic results, which are supported by quantum-mechanical calculations, connect this solid-state phase transition with the mesomeric transition, and this is accompanied by the conformational transformation of anagostic Ni‧‧‧H−C rearrangement and formation of the charge–assisted S-‧‧‧H−C bond under pressure." @default.
- W4214946079 created "2022-03-05" @default.
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- W4214946079 date "2022-03-02" @default.
- W4214946079 modified "2023-09-28" @default.
- W4214946079 title "Resonance between dithiocarbamates and thioureide mesomeres coupled to metal−hydrogen anagostic bond transforming under pressure" @default.
- W4214946079 doi "https://doi.org/10.26434/chemrxiv-2022-h0rrx" @default.
- W4214946079 hasPublicationYear "2022" @default.
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