Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220653587> ?p ?o ?g. }
- W4220653587 abstract "An enantio- and diastereoselective sp3 -sp3 coupling of acyclic/cyclic ketones with dihydrodibenzo-oxazepines has been developed by merging visible light photo-redox- or electro-catalysis with organocatalysis. This approach parallelly utilizes Eosin Y or graphite electrodes for the co-catalyst-free oxidative conversion of dihydrodibenzo-oxazepines to oxazepines, followed by L-Proline catalyzed direct Mannich-type reaction with ketones. A series of enantioenriched dihydrodibenzo-oxazepines have been prepared in high yields and enantioselectivity. This method shows substantial advantages over the existing protocols by using potentially safer starting materials and cheap commercially available catalysts." @default.
- W4220653587 created "2022-04-03" @default.
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- W4220653587 date "2022-04-29" @default.
- W4220653587 modified "2023-10-16" @default.
- W4220653587 title "Stereoselective Oxidative Mannich Reaction of Ketones with Dihydrodibenzo‐Oxazepines via a Merger of Photoredox‐/Electro‐Catalysis with Organocatalysis" @default.
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- W4220653587 doi "https://doi.org/10.1002/cssc.202200415" @default.
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