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- W4220702010 endingPage "118577" @default.
- W4220702010 startingPage "118577" @default.
- W4220702010 abstract "Glycerol dry reforming (GDR) was studied on Ru/La2O3, Ru/ZrO2, and Ru/La2O3–ZrO2 catalysts. Impacts of the support on morphological, electronic and surface chemical properties of the catalysts were comprehensively characterized by TEM, in–situ DRIFTS, XPS, ATR–IR and XRD. Initial (5 h) CO2 conversion at 750 °C and CO2–to–glycerol ratio of 1–4 was ordered as Ru/La2O3 < Ru/ZrO2 < Ru/La2O3–ZrO2. During 72 h stability tests, Ru/ZrO2 deactivated by ~33% due to Ru sintering, structural deformation of the monoclinic zirconia support, and strong metal–support interaction. Under identical conditions, CO2 conversion on Ru/La2O3 decreased by 27% mainly due to dehydroxylation/carbonation of lanthana and severe coking. Lanthana–stabilized tetragonal zirconia phase of Ru/La2O3–ZrO2 led to finely dispersed small oxidic Ru clusters which deactivated by 15% after 72 h and demonstrated unusually high catalytic performance that was on par with the significantly more expensive Rh–based catalysts, which are known with their exceptional activity and stability in GDR." @default.
- W4220702010 created "2022-04-03" @default.
- W4220702010 creator A5000123634 @default.
- W4220702010 creator A5019146785 @default.
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- W4220702010 creator A5027077318 @default.
- W4220702010 creator A5039496082 @default.
- W4220702010 creator A5045844242 @default.
- W4220702010 creator A5086221860 @default.
- W4220702010 date "2022-04-01" @default.
- W4220702010 modified "2023-09-26" @default.
- W4220702010 title "A highly active and stable Ru catalyst for syngas production via glycerol dry reforming: Unraveling the interplay between support material and the active sites" @default.
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- W4220702010 doi "https://doi.org/10.1016/j.apcata.2022.118577" @default.