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• W4220731964 endingPage "2147" @default.
• W4220731964 startingPage "2147" @default.
• W4220731964 abstract "Derivatives of main group elements containing element-element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation. A novel series of digermanes, Ar3Ge-Ge(SiMe3)3, containing aryl (Ar = p-C6H4Me (1), p-C6H4F (2), C6F5 (3)) and trimethylsilyl substituents, was synthesized by the reaction of germyl potassium salt, [(Me3Si)3GeK*THF], with triarylchlorogermanes, Ar3GeCl. The optical and electronic properties of such substituted oligoorganogermanes were investigated spectroscopically by UV/vis absorption spectroscopy and theoretically by DFT calculations. The molecular structures of compounds 1 and 2 were studied by XRD analysis. Conjugation between all structural fragments (Ge-Ge, Ge-Si, Ge-Ar, where Ar is an electron-donating or withdrawing group) was found to affect the properties." @default.
• W4220731964 created "2022-04-03" @default.
• W4220731964 creator A5019490997 @default.
• W4220731964 creator A5044806147 @default.
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• W4220731964 date "2022-03-26" @default.
• W4220731964 modified "2023-09-30" @default.
• W4220731964 title "Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents" @default.
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• W4220731964 doi "https://doi.org/10.3390/molecules27072147" @default.
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