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- W4220763213 abstract "Recently, exploiting a novel supramolecular fabrication pathway have drawn great attention. To this endeavor, we firstly designed and reported an original light-activated platform based on the internal-driven forces of macrocyclic host by hiring the pillar[5]arene as the host molecule ( H ) and phenazine derivatives acting as an energetic guest molecule ( G ). Surprisingly, after adding the H solution into G system, the intensive fluorescence emission of the G molecule rapidly decreased under the irradiation of the UV-light (254 nm) until absolutely quenching. Delightfully, different from the traditional supramolecular host-guest interaction, the fluorescent emission of G molecule could be recovered after irradiating under the nature light. In view of this interesting observations, the interaction mechanism was carefully investigated by a series of characterizations. Those results suggested that the G molecule was easily threaded into the macrocyclic cavity ( H ) under the internal-driven forces induced by the UV-light irradiation, forming a 1:1 host-guest complex. Moreover, taking advantage of this especial feature, the light-activated platform of host–guest complex was further applied for ink-free light-driven printing materials, exhibiting great potential in the real application. We fabricated a novel supramolecular light-activated platform based on the internal-driven forces induced by the UV-light." @default.
- W4220763213 created "2022-04-03" @default.
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- W4220763213 date "2022-12-01" @default.
- W4220763213 modified "2023-10-17" @default.
- W4220763213 title "Fabricating a novel supramolecular light-activated platform based on internal-driven forces induced by the UV-light" @default.
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- W4220763213 doi "https://doi.org/10.1016/j.cclet.2022.03.081" @default.
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