Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220765940> ?p ?o ?g. }
- W4220765940 endingPage "5742" @default.
- W4220765940 startingPage "5735" @default.
- W4220765940 abstract "The model of counterion-induced metallacarborane aggregation in water was verified on sodium bis(1,2-dicarbollide), one of the most studied examples of metallacarboranes. This case study introduces a novel approach in anionic boron cluster self-assembly that resembles the behavior of polyoxometalate nanoions. The key prerequisite of the counterion binding to the aggregates is the strongly uneven charge distribution of cobalt bis(dicarbollide) clusters. Simultaneously, the size of the counterion should fit into the void between the metallacarborane clusters within the aggregate. In consequence, compact pentamers with two bound sodium cations via Coulombic-driven assembly are formed. This behavior cannot be explained solely by the hydrophobic effect─the paradigm of metallacarborane aggregation in the current literature. The pentamers can merge into bigger nanostructures via the second aggregation mechanism that sheds light on the complex behavior of metallacarboranes in water. The proof-of-concept of counterion-induced metallacarborane aggregation and the proposed total description of the self-assembly via the two-process model are results of calorimetry modeling, quantum chemistry calculations, and molecular dynamics simulations." @default.
- W4220765940 created "2022-04-03" @default.
- W4220765940 creator A5021648089 @default.
- W4220765940 creator A5050989717 @default.
- W4220765940 creator A5051072612 @default.
- W4220765940 creator A5054005621 @default.
- W4220765940 creator A5056281112 @default.
- W4220765940 creator A5082967525 @default.
- W4220765940 creator A5083515186 @default.
- W4220765940 creator A5091717691 @default.
- W4220765940 date "2022-03-22" @default.
- W4220765940 modified "2023-10-13" @default.
- W4220765940 title "Counterion-Induced Aggregation of Metallacarboranes" @default.
- W4220765940 cites W1968885557 @default.
- W4220765940 cites W1981745234 @default.
- W4220765940 cites W1997151511 @default.
- W4220765940 cites W2000798385 @default.
- W4220765940 cites W2011215428 @default.
- W4220765940 cites W2017437047 @default.
- W4220765940 cites W2018587140 @default.
- W4220765940 cites W2023271753 @default.
- W4220765940 cites W2038533471 @default.
- W4220765940 cites W2051649380 @default.
- W4220765940 cites W2052573265 @default.
- W4220765940 cites W2065388880 @default.
- W4220765940 cites W2080467735 @default.
- W4220765940 cites W2087219715 @default.
- W4220765940 cites W2093635335 @default.
- W4220765940 cites W2112850441 @default.
- W4220765940 cites W2120530423 @default.
- W4220765940 cites W2125746135 @default.
- W4220765940 cites W2132317577 @default.
- W4220765940 cites W2143981217 @default.
- W4220765940 cites W2148284063 @default.
- W4220765940 cites W2318382249 @default.
- W4220765940 cites W2328817513 @default.
- W4220765940 cites W2418203839 @default.
- W4220765940 cites W2490082537 @default.
- W4220765940 cites W2553518572 @default.
- W4220765940 cites W2557700557 @default.
- W4220765940 cites W2588735259 @default.
- W4220765940 cites W2606619436 @default.
- W4220765940 cites W2736237254 @default.
- W4220765940 cites W2769079189 @default.
- W4220765940 cites W2775546287 @default.
- W4220765940 cites W2781207500 @default.
- W4220765940 cites W2790352034 @default.
- W4220765940 cites W2888187835 @default.
- W4220765940 cites W2893559110 @default.
- W4220765940 cites W2897042286 @default.
- W4220765940 cites W2897131207 @default.
- W4220765940 cites W2972897051 @default.
- W4220765940 cites W2994277041 @default.
- W4220765940 cites W2999033154 @default.
- W4220765940 cites W3017274457 @default.
- W4220765940 cites W3017301669 @default.
- W4220765940 cites W3089067830 @default.
- W4220765940 cites W3113048515 @default.
- W4220765940 cites W3125304574 @default.
- W4220765940 cites W3176880098 @default.
- W4220765940 cites W3203503256 @default.
- W4220765940 cites W4255765039 @default.
- W4220765940 doi "https://doi.org/10.1021/acs.jpcc.2c00107" @default.
- W4220765940 hasPublicationYear "2022" @default.
- W4220765940 type Work @default.
- W4220765940 citedByCount "8" @default.
- W4220765940 countsByYear W42207659402022 @default.
- W4220765940 countsByYear W42207659402023 @default.
- W4220765940 crossrefType "journal-article" @default.
- W4220765940 hasAuthorship W4220765940A5021648089 @default.
- W4220765940 hasAuthorship W4220765940A5050989717 @default.
- W4220765940 hasAuthorship W4220765940A5051072612 @default.
- W4220765940 hasAuthorship W4220765940A5054005621 @default.
- W4220765940 hasAuthorship W4220765940A5056281112 @default.
- W4220765940 hasAuthorship W4220765940A5082967525 @default.
- W4220765940 hasAuthorship W4220765940A5083515186 @default.
- W4220765940 hasAuthorship W4220765940A5091717691 @default.
- W4220765940 hasBestOaLocation W42207659402 @default.
- W4220765940 hasConcept C127413603 @default.
- W4220765940 hasConcept C145148216 @default.
- W4220765940 hasConcept C159467904 @default.
- W4220765940 hasConcept C164866538 @default.
- W4220765940 hasConcept C178790620 @default.
- W4220765940 hasConcept C185592680 @default.
- W4220765940 hasConcept C199360897 @default.
- W4220765940 hasConcept C34814092 @default.
- W4220765940 hasConcept C41008148 @default.
- W4220765940 hasConcept C42360764 @default.
- W4220765940 hasConcept C537181965 @default.
- W4220765940 hasConceptScore W4220765940C127413603 @default.
- W4220765940 hasConceptScore W4220765940C145148216 @default.
- W4220765940 hasConceptScore W4220765940C159467904 @default.
- W4220765940 hasConceptScore W4220765940C164866538 @default.
- W4220765940 hasConceptScore W4220765940C178790620 @default.
- W4220765940 hasConceptScore W4220765940C185592680 @default.
- W4220765940 hasConceptScore W4220765940C199360897 @default.
- W4220765940 hasConceptScore W4220765940C34814092 @default.
- W4220765940 hasConceptScore W4220765940C41008148 @default.