Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220772600> ?p ?o ?g. }
- W4220772600 abstract "Abstract Novel carbonyl dithiolato diiron complexes [Fe 2 (CO) 6‐x L x (μ‐dithiolate)] (x=3, 4), related to the active site of [FeFe]‐hydrogenases, have been synthesized by photolysis of hexacarbonyl species [Fe 2 (CO) 6 (μ‐dithiolate)] (dithiolate={S 2 (CH 2 ) 3 } (pdt), {SCH 2 } 2 NR with R= i Pr (adt i−Pr ) or Bn (adt Bn )). The new compounds were characterized by structural and spectroscopic methods. Variable‐temperature (VT) NMR experiments revealed their fluxionality in solution depending on terminal ligands exchanges and dithiolate bridge motions. Preliminary results on their protonation giving hydride species and their electrochemical properties are reported." @default.
- W4220772600 created "2022-04-03" @default.
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- W4220772600 date "2022-04-14" @default.
- W4220772600 modified "2023-09-23" @default.
- W4220772600 title "Tri‐ and tetra‐substituted derivatives of [Fe2(CO)6(µ‐dithiolate)] as novel dinuclear platforms related to the H‐cluster of [FeFe]H2ases" @default.
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- W4220772600 doi "https://doi.org/10.1002/ejic.202200133" @default.
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