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- W4220773539 abstract "We describe the development of an efficient method for the olefination of hydrazones and oximes. The key design approach that enables this transformation is tuning of the energy/polarity of C=N π-bonds by employing heteroatom functionalities (NR2 , OR). The resulting hydrazones or oximes facilitate olefination with ruthenium alkylidenes. Through this approach, we show that air-stable, commercially available ruthenium alkylidenes provide access to functionalized alkenes (20 examples) in ring-closing reactions with yields up to 88 %." @default.
- W4220773539 created "2022-04-03" @default.
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- W4220773539 date "2022-03-29" @default.
- W4220773539 modified "2023-10-05" @default.
- W4220773539 title "Hydrazone and Oxime Olefination via Ruthenium Alkylidenes" @default.
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- W4220773539 doi "https://doi.org/10.1002/anie.202112101" @default.
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