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- W4220777908 abstract "Abstract We report the synthesis and the reactivity of 1,2,3‐triazolin‐5‐imine type mesoionic imines (MIIs). The MIIs are accessible by a base‐mediated cycloaddition between a substituted acetonitrile and an aromatic azide, methylation by established routes and subsequent deprotonation. C=O‐stretching frequencies in MII−CO 2 and −Rh(CO) 2 Cl complexes were used to determine the overall donor strength. The MIIs are stronger donors than the N‐heterocyclic imines (NHIs). MIIs are excellent ligands for main group elements and transition metals in which they display substituent‐induced fluorine‐specific interactions and undergo C−H activation. DFT calculations gave insights into the frontier orbitals of the MIIs. The calculations predict a relatively small HOMO–LUMO gap compared to other related ligands. MIIs are potentially able to act as both π‐donor and π‐acceptor ligands. This report highlights the potential of MIIs to display exciting properties with a huge potential for future development." @default.
- W4220777908 created "2022-04-03" @default.
- W4220777908 creator A5020335865 @default.
- W4220777908 creator A5034978213 @default.
- W4220777908 creator A5059771482 @default.
- W4220777908 creator A5071507672 @default.
- W4220777908 creator A5069472168 @default.
- W4220777908 date "2022-04-19" @default.
- W4220777908 modified "2023-10-08" @default.
- W4220777908 title "Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates" @default.
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