Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220781194> ?p ?o ?g. }
- W4220781194 endingPage "2923" @default.
- W4220781194 startingPage "2911" @default.
- W4220781194 abstract "The rational design and precise synthesis of aggregation-induced emission (AIE) active polymers with diverse macromolecular structures are crucial to their applications in various fields. Herein, four tetraphenylethylene (TPE) bromopropionate initiators with the number of initiation sites of n = 1–4 were synthesized for the first time and applied in the Cu(0)-mediated single-electron transfer living radical polymerization (SET-LRP) of methyl acrylate (MA) and tert-butyl acrylate (tBA). Well-controlled polymerization and high chain-end fidelity were confirmed by 1H NMR and GPC. The produced polymers had diverse topology (linear/star) and the location of TPE moiety (chain-end/midchain/core), which were all precisely dictated by initiator structure. The macromolecular structure had a remarkable effect on the AIE properties of TPE-(PMA)n in THF/H2O mixtures and TPE-(PAA)n (obtained after deprotecting tert-butyl groups from TPE-(PtBA)n) in the B-R buffer solutions of different pH values. The fundamental insights gained into the macromolecular structure–AIE property correlation in our work are important for the design of AIE-active polymer-based functional materials." @default.
- W4220781194 created "2022-04-03" @default.
- W4220781194 creator A5050414657 @default.
- W4220781194 creator A5067543084 @default.
- W4220781194 creator A5068741782 @default.
- W4220781194 creator A5076675295 @default.
- W4220781194 creator A5090269955 @default.
- W4220781194 date "2022-03-17" @default.
- W4220781194 modified "2023-10-16" @default.
- W4220781194 title "Precise Synthesis of Structurally Diverse Aggregation-Induced Emission-Active Polyacrylates by Cu(0)-Catalyzed SET-LRP with Macromolecular Structure-Correlated Emission" @default.
- W4220781194 cites W1973762887 @default.
- W4220781194 cites W2002640109 @default.
- W4220781194 cites W2005231216 @default.
- W4220781194 cites W2015831478 @default.
- W4220781194 cites W2019583836 @default.
- W4220781194 cites W2032185182 @default.
- W4220781194 cites W2043924688 @default.
- W4220781194 cites W2047407007 @default.
- W4220781194 cites W2073939352 @default.
- W4220781194 cites W2075042367 @default.
- W4220781194 cites W2079011492 @default.
- W4220781194 cites W2080589373 @default.
- W4220781194 cites W2085056001 @default.
- W4220781194 cites W2104781674 @default.
- W4220781194 cites W2107072208 @default.
- W4220781194 cites W2131801486 @default.
- W4220781194 cites W2137490548 @default.
- W4220781194 cites W2159182565 @default.
- W4220781194 cites W2169892080 @default.
- W4220781194 cites W2230039548 @default.
- W4220781194 cites W2288268375 @default.
- W4220781194 cites W2316585167 @default.
- W4220781194 cites W2337610347 @default.
- W4220781194 cites W2461712522 @default.
- W4220781194 cites W2511186273 @default.
- W4220781194 cites W2529427105 @default.
- W4220781194 cites W2544423921 @default.
- W4220781194 cites W2604153043 @default.
- W4220781194 cites W2606127690 @default.
- W4220781194 cites W2614536069 @default.
- W4220781194 cites W2737636993 @default.
- W4220781194 cites W2750981523 @default.
- W4220781194 cites W2754346359 @default.
- W4220781194 cites W2768177271 @default.
- W4220781194 cites W2769216568 @default.
- W4220781194 cites W2781450043 @default.
- W4220781194 cites W2783601122 @default.
- W4220781194 cites W2798064651 @default.
- W4220781194 cites W2801399464 @default.
- W4220781194 cites W2805149455 @default.
- W4220781194 cites W2811194605 @default.
- W4220781194 cites W2870842241 @default.
- W4220781194 cites W2902406108 @default.
- W4220781194 cites W2915450178 @default.
- W4220781194 cites W2917811078 @default.
- W4220781194 cites W2966561372 @default.
- W4220781194 cites W2980281614 @default.
- W4220781194 cites W2987505784 @default.
- W4220781194 cites W2994893180 @default.
- W4220781194 cites W3003210710 @default.
- W4220781194 cites W3004460071 @default.
- W4220781194 cites W3023393699 @default.
- W4220781194 cites W3034959675 @default.
- W4220781194 cites W3036062741 @default.
- W4220781194 cites W3041965332 @default.
- W4220781194 cites W3042475438 @default.
- W4220781194 cites W3111605245 @default.
- W4220781194 cites W3121653189 @default.
- W4220781194 cites W3133826925 @default.
- W4220781194 cites W3159852047 @default.
- W4220781194 doi "https://doi.org/10.1021/acs.macromol.2c00264" @default.
- W4220781194 hasPublicationYear "2022" @default.
- W4220781194 type Work @default.
- W4220781194 citedByCount "5" @default.
- W4220781194 countsByYear W42207811942023 @default.
- W4220781194 crossrefType "journal-article" @default.
- W4220781194 hasAuthorship W4220781194A5050414657 @default.
- W4220781194 hasAuthorship W4220781194A5067543084 @default.
- W4220781194 hasAuthorship W4220781194A5068741782 @default.
- W4220781194 hasAuthorship W4220781194A5076675295 @default.
- W4220781194 hasAuthorship W4220781194A5090269955 @default.
- W4220781194 hasConcept C111998727 @default.
- W4220781194 hasConcept C121120078 @default.
- W4220781194 hasConcept C121332964 @default.
- W4220781194 hasConcept C15920480 @default.
- W4220781194 hasConcept C166940927 @default.
- W4220781194 hasConcept C178790620 @default.
- W4220781194 hasConcept C185592680 @default.
- W4220781194 hasConcept C188027245 @default.
- W4220781194 hasConcept C204389451 @default.
- W4220781194 hasConcept C2776227087 @default.
- W4220781194 hasConcept C2776568683 @default.
- W4220781194 hasConcept C2778004933 @default.
- W4220781194 hasConcept C2778987444 @default.
- W4220781194 hasConcept C2779989194 @default.
- W4220781194 hasConcept C44228677 @default.
- W4220781194 hasConcept C521977710 @default.
- W4220781194 hasConcept C55493867 @default.