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• W4220784966 abstract "We report herein the synthesis and application of enantiopure C2 -symmetric primary amine-1,3-bis-thiourea organocatalysts in enantioselective conjugate 1,4-Michael addition of carbonyl containing nucleophiles, to nitroalkenes and N-phenylmaleimide, leading to final products in good enantioselectivities (up to 99%) and yields (up to 99%). We propose supramolecular noncovalent interactions within the organocatalyst's cleft between the substrate and the catalyst, via hydrogen bonding. Supramolecular interaction thus lowers the transition state energy mimicking an enzyme. Mechanism underlying our experimental results is supported by theorical calculations." @default.
• W4220784966 created "2022-04-03" @default.
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• W4220784966 date "2022-03-18" @default.
• W4220784966 modified "2023-10-14" @default.
• W4220784966 title "Chiral C₂‐symmetric bis‐thioureas as enzyme mimics in enantioselective Michael addition" @default.
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• W4220784966 doi "https://doi.org/10.1002/chir.23438" @default.
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