FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220789910> ?p ?o ?g. }

• W4220789910 abstract "Abstract To improve the flame retardancy of vinyl epoxy (VE) resins more effectively, a half‐cage and cage structure polyhedral oligomeric silsesquioxanes (P/N‐POSS) containing phosphorus and nitrogen was synthesized by a one‐step Kabachnik‐Fields reaction from paraformaldehyde, 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) and 3‐aminopropyltriethoxysilane. It was then blended with tetrabutyl titanate (TBT) in VE resins to construct a phosphorus‐nitrogen‐silicon‐titanium synergy flame retardant system. P/N‐POSS was well dispersed in the VE matrix at low loadings (≤4 wt%). With the addition of only 4 wt% P/N‐POSS and 0.2 wt% TBT, the LOI value reached 29.2 and the UL‐94 grade passed V‐1 rating. Moreover, compared with VE‐0, the peak heat release rate, total heat release, smoke production rate and total smoke production decreased significantly. The investigations on pyrolysis volatiles and char residue of cured VE composites revealed that the excellent flame retardancy of the VE composites were due to the superior free radical capturing ability, the dilution effect of P/N‐POSS in the gas phase, and the promoting the carbonation effect of P/N‐POSS, the catalyzing char formation ability of TBT in the condensed phase. Meanwhile, VE composites exhibited improved mechanical properties, thermal stabilities and retained the low viscosity and good processability of VE resins." @default.
• W4220789910 created "2022-04-03" @default.
• W4220789910 creator A5002072271 @default.
• W4220789910 creator A5009232538 @default.
• W4220789910 creator A5047047130 @default.
• W4220789910 creator A5052899933 @default.
• W4220789910 creator A5056193097 @default.
• W4220789910 creator A5059886125 @default.
• W4220789910 creator A5060821325 @default.
• W4220789910 creator A5080790786 @default.
• W4220789910 creator A5087432052 @default.
• W4220789910 creator A5089619087 @default.
• W4220789910 date "2022-03-22" @default.
• W4220789910 modified "2023-10-17" @default.
• W4220789910 title "Synergistic effects of a half‐cage and cage structure phosphorus and nitrogen‐containing <scp>POSS</scp> with tetrabutyl titanate on flame retardancy of vinyl epoxy resins" @default.
• W4220789910 cites W1090590421 @default.
• W4220789910 cites W1216549567 @default.
• W4220789910 cites W1809690590 @default.
• W4220789910 cites W1972342156 @default.
• W4220789910 cites W1988069405 @default.
• W4220789910 cites W1993896470 @default.
• W4220789910 cites W2003073160 @default.
• W4220789910 cites W2006437647 @default.
• W4220789910 cites W2010098110 @default.
• W4220789910 cites W2012222717 @default.
• W4220789910 cites W2017524793 @default.
• W4220789910 cites W2023803893 @default.
• W4220789910 cites W2031358845 @default.
• W4220789910 cites W2031868496 @default.
• W4220789910 cites W2032040817 @default.
• W4220789910 cites W2037622320 @default.
• W4220789910 cites W2042047515 @default.
• W4220789910 cites W2052159923 @default.
• W4220789910 cites W2062763730 @default.
• W4220789910 cites W2065265662 @default.
• W4220789910 cites W2070254906 @default.
• W4220789910 cites W2072977946 @default.
• W4220789910 cites W2078329381 @default.
• W4220789910 cites W2079001430 @default.
• W4220789910 cites W2087774909 @default.
• W4220789910 cites W2088431363 @default.
• W4220789910 cites W2089176637 @default.
• W4220789910 cites W2093616343 @default.
• W4220789910 cites W2139457924 @default.
• W4220789910 cites W2227059462 @default.
• W4220789910 cites W2265470240 @default.
• W4220789910 cites W2469823244 @default.
• W4220789910 cites W2473447566 @default.
• W4220789910 cites W2474609711 @default.
• W4220789910 cites W2493981352 @default.
• W4220789910 cites W2537091229 @default.
• W4220789910 cites W2538693027 @default.
• W4220789910 cites W2616568319 @default.
• W4220789910 cites W2737821188 @default.
• W4220789910 cites W2744140792 @default.
• W4220789910 cites W2757696004 @default.
• W4220789910 cites W2762451068 @default.
• W4220789910 cites W2780558851 @default.
• W4220789910 cites W2783106188 @default.
• W4220789910 cites W2783410351 @default.
• W4220789910 cites W2790159354 @default.
• W4220789910 cites W2810267453 @default.
• W4220789910 cites W2885009098 @default.
• W4220789910 cites W2887560618 @default.
• W4220789910 cites W2887609324 @default.
• W4220789910 cites W2899195462 @default.
• W4220789910 cites W2943024801 @default.
• W4220789910 cites W2950503560 @default.
• W4220789910 cites W2953531679 @default.
• W4220789910 cites W2954645968 @default.
• W4220789910 cites W2961909590 @default.
• W4220789910 cites W2983057075 @default.
• W4220789910 cites W2987992668 @default.
• W4220789910 cites W2991023833 @default.
• W4220789910 cites W2994441919 @default.
• W4220789910 cites W2997749996 @default.
• W4220789910 cites W2999329167 @default.
• W4220789910 cites W3000667998 @default.
• W4220789910 cites W3004126162 @default.
• W4220789910 cites W3011860189 @default.
• W4220789910 cites W3014909533 @default.
• W4220789910 cites W3015079026 @default.
• W4220789910 cites W3034720520 @default.
• W4220789910 cites W3036660494 @default.
• W4220789910 cites W3045036033 @default.
• W4220789910 cites W3047582754 @default.
• W4220789910 cites W3092483461 @default.
• W4220789910 cites W3098489221 @default.
• W4220789910 cites W3106942724 @default.
• W4220789910 cites W3120295420 @default.
• W4220789910 cites W3123330312 @default.
• W4220789910 cites W3154151365 @default.
• W4220789910 cites W3159609323 @default.
• W4220789910 cites W52974666 @default.
• W4220789910 cites W794922598 @default.
• W4220789910 doi "https://doi.org/10.1002/app.52342" @default.
• W4220789910 hasPublicationYear "2022" @default.
• W4220789910 type Work @default.
• W4220789910 citedByCount "3" @default.
• W4220789910 countsByYear W42207899102022 @default.

• next