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• W4220791487 startingPage "2055" @default.
• W4220791487 abstract "The preparation of 2,2,2-trifluoroacetaldehyde O-(aryl)oxime, a previously inaccessible precursor of trifluoroacetonitrile, via reaction of hydroxylamine and trifluoroacetaldehyde hydrate is reported. This precursor released CF3CN in quantitative yield under mildly basic conditions. The precursor was successfully used in the synthesis of trifluoromethylated oxadiazoles. The facile, cost-effective, scalable, and recyclable procedure makes these trifluoroacetonitrile precursors generally applicable." @default.
• W4220791487 created "2022-04-03" @default.
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• W4220791487 date "2022-03-10" @default.
• W4220791487 modified "2023-10-13" @default.
• W4220791487 title "2,2,2-Trifluoroacetaldehyde <i>O</i>-(Aryl)oxime: A Precursor of Trifluoroacetonitrile" @default.
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• W4220791487 doi "https://doi.org/10.1021/acs.orglett.2c00637" @default.
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