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- W4220791862 endingPage "132938" @default.
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- W4220791862 abstract "• Asymmetrically tetra substituted Zn phthalocyanines bearing alkynyl ( 1 ) and fluorine substituents ( 2 and 3 ) were synthesized. • The complexes were conjugated to CoWO 4 nanoparticles and employed for photocatalytic degradation of tetracycline • Complex 1 showed higher activity towards the photocatalytic activity compared to complexes 2 and 3. • The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model. This work focused on syntheses of novel asymmetrically tetra substituted Zn phthalocyanines (ZnPc) each containing a single carboxyl group, with the other substituents bearing alkynyl (complex 1 ) and fluorine containing groups (complexes 2 and 3 ). The complexes were conjugated to cobalt tungstate nanoparticles and employed as efficient photocatalysts for degradation of tetracycline in water. ZnPc complexes and their conjugates showed good photophysical and photochemical properties behaviour with complex 1 giving higher triplet and singlet oxygen quantum yields compared to 2 and 3 . Complex 1 showed higher activity towards the photodegradation of tetracycline compared to complexes 2 and 3 , with higher k obs and initial rates for the former. The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model." @default.
- W4220791862 created "2022-04-03" @default.
- W4220791862 creator A5017410847 @default.
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- W4220791862 date "2022-08-01" @default.
- W4220791862 modified "2023-09-26" @default.
- W4220791862 title "Photodegradation of tetracycline by asymmetrical zinc(II)phthalocyanines conjugated to cobalt tungstate nanoparticles" @default.
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- W4220791862 doi "https://doi.org/10.1016/j.molstruc.2022.132938" @default.
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