Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220793905> ?p ?o ?g. }
- W4220793905 endingPage "118259" @default.
- W4220793905 startingPage "118259" @default.
- W4220793905 abstract "Polyfluoroalkyl and perfluoroalkyl chemicals (PFCs) widely used in lubricants, surfactant, textiles, paper coatings, cosmetics, and fire-fighting foams can release a large deal of organics contaminants into wastewater and pose great risks to the health of humans and eco-environments. Although advanced oxidation processes can effectively deconstruct various organic contaminants via reactive radicals, the stable structure of PFCs makes it difficult to be degraded. Here, we confirm that electrochemical oxidation process coupled with peroxymonosulfate (PMS) reaction can efficiently destroy stable structure of PFCs via electron transfer and meanwhile completely degrade PFCs via generated active radicals. We further studies via capturing and scavenging radicals, and DFT calculations find that electron hydroxyl radials play a dominant role in degrading PFCs. Based on the calculations of adsorption energy and molecular orbital energy we further demonstrate that many active sites on the surface of Ti4O7 (1 0 4) plane can rapidly take part in electrochemical reaction for generating radials and removing organic contaminants. These results give a promising insight towards high-effective and deep degradation of PFCs via electrochemical reaction coupled with advanced oxidation processes, as well as providing guidance and technical support for the remove of multiple organic contaminants." @default.
- W4220793905 created "2022-04-03" @default.
- W4220793905 creator A5003162639 @default.
- W4220793905 creator A5012262994 @default.
- W4220793905 creator A5043858190 @default.
- W4220793905 creator A5053608602 @default.
- W4220793905 creator A5055949283 @default.
- W4220793905 creator A5058595707 @default.
- W4220793905 creator A5064105259 @default.
- W4220793905 creator A5084754656 @default.
- W4220793905 creator A5087318320 @default.
- W4220793905 creator A5087592842 @default.
- W4220793905 creator A5088477238 @default.
- W4220793905 date "2022-05-01" @default.
- W4220793905 modified "2023-10-05" @default.
- W4220793905 title "Exploration of perfluorooctane sulfonate degradation properties and mechanism via electron-transfer dominated radical process" @default.
- W4220793905 cites W1970127494 @default.
- W4220793905 cites W2007395042 @default.
- W4220793905 cites W2014286678 @default.
- W4220793905 cites W2083222334 @default.
- W4220793905 cites W2092157292 @default.
- W4220793905 cites W2132525235 @default.
- W4220793905 cites W2301791738 @default.
- W4220793905 cites W2526174265 @default.
- W4220793905 cites W2761051420 @default.
- W4220793905 cites W2770822733 @default.
- W4220793905 cites W2781198865 @default.
- W4220793905 cites W2789856719 @default.
- W4220793905 cites W2789906405 @default.
- W4220793905 cites W2795208149 @default.
- W4220793905 cites W2841606001 @default.
- W4220793905 cites W2888827392 @default.
- W4220793905 cites W2898810201 @default.
- W4220793905 cites W2916822676 @default.
- W4220793905 cites W2929918033 @default.
- W4220793905 cites W2938576811 @default.
- W4220793905 cites W2942647455 @default.
- W4220793905 cites W2942718301 @default.
- W4220793905 cites W2952707340 @default.
- W4220793905 cites W2955078992 @default.
- W4220793905 cites W2984712026 @default.
- W4220793905 cites W2985704251 @default.
- W4220793905 cites W2987832273 @default.
- W4220793905 cites W2991483860 @default.
- W4220793905 cites W2994732061 @default.
- W4220793905 cites W3008296763 @default.
- W4220793905 cites W3024383217 @default.
- W4220793905 cites W3028030581 @default.
- W4220793905 cites W3033040898 @default.
- W4220793905 cites W3036507073 @default.
- W4220793905 cites W3040225007 @default.
- W4220793905 cites W3087613412 @default.
- W4220793905 cites W3088430873 @default.
- W4220793905 cites W3090242787 @default.
- W4220793905 cites W3106588142 @default.
- W4220793905 cites W3112559197 @default.
- W4220793905 cites W3117707928 @default.
- W4220793905 cites W3119575060 @default.
- W4220793905 cites W3119760521 @default.
- W4220793905 cites W3122819060 @default.
- W4220793905 cites W3124914184 @default.
- W4220793905 cites W3126132100 @default.
- W4220793905 cites W3129376735 @default.
- W4220793905 cites W3132048095 @default.
- W4220793905 cites W3160202374 @default.
- W4220793905 cites W3163361401 @default.
- W4220793905 cites W3180790249 @default.
- W4220793905 cites W3190042211 @default.
- W4220793905 cites W3206077653 @default.
- W4220793905 cites W3208798707 @default.
- W4220793905 cites W3211900434 @default.
- W4220793905 cites W3212429971 @default.
- W4220793905 doi "https://doi.org/10.1016/j.watres.2022.118259" @default.
- W4220793905 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35294910" @default.
- W4220793905 hasPublicationYear "2022" @default.
- W4220793905 type Work @default.
- W4220793905 citedByCount "19" @default.
- W4220793905 countsByYear W42207939052022 @default.
- W4220793905 countsByYear W42207939052023 @default.
- W4220793905 crossrefType "journal-article" @default.
- W4220793905 hasAuthorship W4220793905A5003162639 @default.
- W4220793905 hasAuthorship W4220793905A5012262994 @default.
- W4220793905 hasAuthorship W4220793905A5043858190 @default.
- W4220793905 hasAuthorship W4220793905A5053608602 @default.
- W4220793905 hasAuthorship W4220793905A5055949283 @default.
- W4220793905 hasAuthorship W4220793905A5058595707 @default.
- W4220793905 hasAuthorship W4220793905A5064105259 @default.
- W4220793905 hasAuthorship W4220793905A5084754656 @default.
- W4220793905 hasAuthorship W4220793905A5087318320 @default.
- W4220793905 hasAuthorship W4220793905A5087592842 @default.
- W4220793905 hasAuthorship W4220793905A5088477238 @default.
- W4220793905 hasConcept C107872376 @default.
- W4220793905 hasConcept C123669783 @default.
- W4220793905 hasConcept C127413603 @default.
- W4220793905 hasConcept C139066938 @default.
- W4220793905 hasConcept C147789679 @default.
- W4220793905 hasConcept C150394285 @default.
- W4220793905 hasConcept C161790260 @default.