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- W4220801412 abstract "Phospholipid monolayers formed at oil-water interfaces are used for various biological applications. However, monolayer structures are not well understood. Herein, we investigated hydrocarbon partitioning in 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine monolayers formed at hydrocarbon-water interfaces using fluorescence microscopy and pendant drop tensiometry. The monolayers strongly interacted with squalene, n-hexadecane, n-tetradecane, n-dodecane, n-decane, and n-butylcyclohexane. These alkane and alkylcyclohexane molecules remained within the monolayers during area compression. In contrast, the monolayers interacted weakly with n-pentylbenzene and n-butylbenzene. These alkylbenzenes were gradually removed from the monolayers upon area compression and were completely expelled at an area per lipid of ∼70 Å2. Surface pressure analysis indicated that the ability of hydrocarbons to penetrate the monolayers was enhanced in the order of n-butylbenzene < n-pentylbenzene < n-butylcyclohexane < n-hexadecane." @default.
- W4220801412 created "2022-04-03" @default.
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- W4220801412 date "2022-03-15" @default.
- W4220801412 modified "2023-09-27" @default.
- W4220801412 title "Hydrocarbon Penetration into Phospholipid Monolayers Formed at Hydrocarbon–Water Interfaces" @default.
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- W4220801412 doi "https://doi.org/10.1021/acs.langmuir.1c03269" @default.
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