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- W4220804517 abstract "Abstract The metal‐free catalytic hydrogenolysis of silyl triflates and halides (I, Br) to hydrosilanes is unlocked by using arylborane Lewis acids as catalysts. In the presence of a nitrogen base, the catalyst acts as a Frustrated Lewis Pair (FLP) able to split H 2 and generate a boron hydride intermediate capable of reducing (pseudo)halosilanes. This metal‐free organocatalytic system is competitive with metal‐based catalysts and enables the formation of a variety of hydrosilanes at room temperature in high yields (>85 %) under a low pressure of H 2 (≤10 bar)." @default.
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- W4220804517 date "2022-04-05" @default.
- W4220804517 modified "2023-09-30" @default.
- W4220804517 title "Metal‐free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes" @default.
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- W4220804517 doi "https://doi.org/10.1002/ange.202200911" @default.
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